2010, Number 2
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Rev Odont Mex 2010; 14 (2)
Residual monomer determination in three different brands of denture base resin by means of gas chromatograph
Solórzano LF, Venegas LRD, Moreno MV, López MS
Language: Spanish
References: 15
Page: 91-98
PDF size: 463.95 Kb.
ABSTRACT
Among the processing techniques of the acrylic resin for dental use in Mexico, it has not been seen the comparative determination of the residual monomer. Whereas the proper processing having the residual monomer in tolerable concentration ranks, for many patients the irritated tissue and the allergic reaction are consequences of the high levels of residual monomer that exist in alternative techniques and this can be of clinical consent. We determined the residual monomer of the heat-polymerized acrylic resin using the gas chromatography for three different registered trademark for denture base. The evaluated materials are: SR Ivocap
® Plus High Impact (Ivoclar Vivadent), Palaxpress
® (Heraeus Kulzer) y ProBase Hot Trial Kit
® (Ivoclar Vivadent). Each specimen was processed with the norms and the specification of the manufacturer. In order to carry out this Study nine samples were processed, which were dissolved in tetrahydrofuran (THF) to be analyzed in the gas chromatograph. Given the results that were obtained, all the materials fulfilled the requirements that ISO 1567-1999 establishes having a lower value than 2.2% of residual monomer, among the materials tested the highest value reported was 0.203%.
REFERENCES
Rodney D. Phoenix. Materiales para base de dentaduras. Clin Odontol Norteam 1996; 1: 119-260.
Graig RG. Materiales de odontología restauradora. Capítulo 6: Polímeros y polimerización. 1ª Ed. México: Editorial Harcourt Brace; 1998: 127-35
Guzmán A. Estudio técnico económico en la recuperación de monómero de metacrilato de metilo a partir de polímero. México. Facultad de Química 1974: 150.
McCabe JF, Basker RM. Tissue sensitivity to acrylic resin: a method of measuring the residual monomer content and its clinical application. Br Dent J 1976; 140: 347-50.
Lung CYK, Darvell BW. Methyl methacrylate in poly (methyl methacrylate) –validation of direct injection gas chromatography. J Chromatogr A 2004; 1061(1): 93-8.
Shim JS, Watts DC. Residual monomer concentrations in denture-base acrylic resin after an additional, soft-liner, heat-cure cycle. Dent Mater 1999; 15(4): 296-300.
ISO 1567:1999, Dentristry-Denture base polymers, Third edition.
Instrucciones de uso SR Ivocap® System, Ivoclar Vivadent AG, Schaan/Liechtenstein. 2005.
Instrucciones de uso Palaxpress®, Heraeus Kulzer, Hanau. Alemania.
Instrucciones de uso Probase Hot®, Ivoclar Vivadent AG, Schaan/Liechtenstein. 06-2005.
Sadamori S, Ganefiyanti T. Influence of thickness and location on the residual monomer content of denture base cured by three processing methods. J Prosthet Dent 1994; 72(1): 19-22.
Kalipçilar B, Karaaaçliolu L. Evaluation of the level of residual monomer in acrylic denture base materials having different polymerization properties. J Oral Rehabil 1991; 18(5): 399-401.
Miettinen VM, Vallittu PK. Release of residual methyl methacrylate into water from glass fibre-poly(methylmethacrylate) composite used in dentures. Biomaterials 1997; 18: 181-5.
Lassila LV, Vallittu PK. Denture base polymer Alldent Sinomer: mechanical properties, water sorption and release of residual compounds. J Oral Rehabil 2001; 28: 607-13.
Gonçalves TS, Morganti MA. Allergy to auto-polymerized acrylic resin in an orthodontic patient. Am J Orthod Dentofacial Orthop 2006; 129(3): 431-5.