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TIP Revista Especializada en Ciencias Químico-Biológicas

2019, Número 1

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TIP Rev Esp Cienc Quim Biol 2019; 22 (1)


Epoxidación enzimática de metil ésteres de ácidos grasos de origen vegetal y sus aplicaciones como alternativa para sustituir a los derivados del petróleo

Sustaita-Rodríguez A, Rocha-Gutiérrez BA, García-Triana A, Ramos-Sánchez VH, Beltrán-Piña BG, Chávez-Flores D

Idioma: Español
Referencias bibliográficas: 109
Paginas: 1-17
Archivo PDF: 1245.00 Kb.


RESUMEN

Recientemente, la modificación de aceites vegetales para obtener ésteres metílicos de ácidos grasos (FAMEs) o biodiesel ha emergido como una alternativa para la sustitución de los derivados del petróleo, esto debido a los problemas ambientales y de salud que genera su uso. Debido a su estructura química es posible epoxidar estas moléculas y usarlas directamente para producir plastificantes o lubricantes. Sin embargo, éstas también pueden ser sujetas a modificaciones para mejorar sus propiedades y el de servir como intermediarias para la síntesis de poliuretanos. Puesto que los métodos convencionales para la producción de epóxidos también son una fuente potencial de contaminación, se ha sugerido el uso de catalizadores enzimáticos como una alternativa sostenible o “Verde” para su preparación, ya que permiten obtener productos con alta pureza y mejores rendimientos. Este artículo presenta una revisión de la literatura disponible centrándose en la epoxidación enzimática de los FAMEs, así como sus principales aplicaciones.


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